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Thermal reffusivity: uncovering phonon behavior, structural defects, and domain size

Yangsu XIE, Bowen ZHU, Jing LIU, Zaoli XU, Xinwei WANG

《能源前沿(英文)》 2018年 第12卷 第1期   页码 143-157 doi: 10.1007/s11708-018-0520-z

摘要: To understand the relation between different nanostructures and thermal properties, a simple yet effective model is in demand for characterizing the underlying phonons and electrons scattering mechanisms. Herein, we make a systematic review on the newly developed thermal reffusivity theory. Like electrical resistivity which has been historically used as a theory for analyzing structural domain size and defect levels of metals, the thermal reffusivity can also uncover phonon behavior, structure defects and domain size of materials. We highlight that this new theory can be used for not only metals, but also nonmetals, even for amorphous materials. From the thermal reffusivity against temperature curves, the Debye temperature of the material and the ideal thermal diffusivity of single perfect crystal can be evaluated. From the residual thermal reffusivity at the 0 K limit, the structural thermal domain (STD) size of crystalline and amorphous materials can be obtained. The difference of white hair and normal black hair from heat conduction perspective is reported for the first time. Loss of melanin results in a worse thermal protection and a larger STD size in the white hair. By reviewing the different variation of thermal reffusivity against decreasing temperature profiles, we conclude that they reflected the structural connection in the materials. Ultimately, the future application of thermal reffusivity theory in studying 2D materials and amorphous materials is discussed.

关键词: thermal reffusivity theory     phonon behavior     structure defects     structural thermal domain (STD) size     2D material     amorphous material    

Influence evaluation of loading conditions during pressurized thermal shock transients based on thermal-hydraulicsand structural analyses

Jinya KATSUYAMA, Shumpei UNO, Tadashi WATANABE, Yinsheng LI

《机械工程前沿(英文)》 2018年 第13卷 第4期   页码 563-570 doi: 10.1007/s11465-018-0487-9

摘要:

The thermal hydraulic (TH) behavior of coo-lant water is a key factor in the structural integrity assessments on reactor pressure vessels (RPVs) of pressurized water reactors (PWRs) under pressurized thermal shock (PTS) events, because the TH behavior may affect the loading conditions in the assessment. From the viewpoint of TH behavior, configuration of plant equipment and their dimensions, and operator action time considerably influence various parameters, such as the temperature and flow rate of coolant water and inner pressure. In this study, to investigate the influence of the operator action time on TH behavior during a PTS event, we developed an analysis model for a typical Japanese PWR plant, including the RPV and the main components of both primary and secondary systems, and performed TH analyses by using a system analysis code called RELAP5. We applied two different operator action times based on the Japanese and the United States (US) rules: Operators may act after 10 min (Japanese rules) and 30 min (the US rules) after the occurrence of PTS events. Based on the results of TH analysis with different operator action times, we also performed structural analyses for evaluating thermal-stress distributions in the RPV during PTS events as loading conditions in the structural integrity assessment. From the analysis results, it was clarified that differences in operator action times significantly affect TH behavior and loading conditions, as the Japanese rule may lead to lower stresses than that under the US rule because an earlier operator action caused lower pressure in the RPV.

关键词: structural integrity     reactor pressure vessel     pressurized thermal shock     thermal hydraulic analysis     pressurized water reactor     weld residual stress    

Variation in humic and fulvic acids during thermal sludge treatment assessed by size fractionation, elementary

Yuning YANG,Huan LI,Jinyi LI

《环境科学与工程前沿(英文)》 2014年 第8卷 第6期   页码 854-862 doi: 10.1007/s11783-014-0755-9

摘要: Thermal pretreatment can be applied to sludge anaerobic digestion or dewatering. To analyze the variation in humic substances during thermal sludge treatment, sludge humic and fulvic acids were extracted before and after 30-min thermal treatment at 180°C, and then their contents, molecular weight distributions, elementary compositions, and spectral characteristics were compared. The results showed that the total contents of humic and fulvic acids in the sludge almost remained constant during thermal treatment, but 35% of humic and fulvic acids were dissolved from the sludge solids. Moreover, both humic and fulvic acids were partly decomposed and 32% of humic acids were converted to fulvic acids. The median value of the molecular weights of humic acids decreased from 81 to 41 kDa and that of fulvic acids decreased from 15 to 2 kDa. Besides the reduction in molecular size, the chemical structures of humic and fulvic acids also exhibited a slight change, i.e. some oxygen functional groups disappeared and aromatic structures increased after thermal sludge treatment.

关键词: sludge     thermal treatment     humic acids     fulvic acids    

A super-element approach for structural identification in time domain

LI Jie, ZHAO Xin

《机械工程前沿(英文)》 2006年 第1卷 第2期   页码 215-221 doi: 10.1007/s11465-006-0004-4

摘要: For most time-domain identification methods, a complete measurement for unique identification results is required for structural responses. However, the number of transducers is commonly far less than the number of structural degrees of freedom (DOFs) in practical applications, and thus make the time-domain identification methods rarely feasible for practical systems. A super-element approach is proposed in this study to identify the structural parameters of a large-scale structure in the time domain. The most interesting feature of the proposed super-element approach is its divide-and-conquer ability, which can be applied to identify large-scale structures using a relatively small number of transducers. The super-element model used for time domain identification is first discussed in this study. Then a parameterization procedure based on the sensitivities of response forces is introduced to establish the identification equations of super-elements. Some principles are suggested on effective decomposing of the whole structure into super-elements for identification purposes. Numerical simulations are conducted at the end of this study. The numerical results show that all structural parameters can be identified using a relatively small number of transducers, and the computational time can also be greatly shortened.

关键词: numerical     effective decomposing     parameterization procedure     divide-and-conquer ability     time-domain identification    

Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

《化学科学与工程前沿(英文)》 2017年 第11卷 第2期   页码 220-230 doi: 10.1007/s11705-017-1624-4

摘要: Clindamycin phosphate (CP), an antibacterial agent, has been reported to form several solid-state forms. The crystal structures of two CP solvates, a dimethyl sulfoxide (DMSO) solvate and a methanol/water solvate (solvate V), have been determined by single crystal X-ray diffraction. The properties and transformations of these forms were characterized by powder X-ray diffraction, Single-crystal X-ray diffraction, differential scanning calorimetry, thermo gravimetric analysis, hot-stage microscopy, and dynamic vapor sorption. Very different hydrogen bonding networks exist among the host-host and host-solvent molecules in the two crystal structures, resulting in different moisture stabilities. The thermal stabilities of the two solvates upon heating and desolvation were also studied. When the temperature was above the boiling point of methanol, solvate V converted to a polymorphic phase after a one step desolvation process, whereas the desolvation temperature of the DMSO solvate was below the boiling point of DMSO. At the relative humidity above 43%, the DMSO solvate transformed to a hydrate at 25 °C. In contrast, solvate V did not transform at any of the humidities studied.

关键词: clindamycin phosphate     solvate     crystal structure     thermal stability     moisture stability    

Structural prediction of porcine sialoadhesin V-set Ig-like domain sheds some light on its role in porcine

Jie HOU,Rui LI,Hongfang MA,Songlin QIAO,Gaiping ZHANG

《农业科学与工程前沿(英文)》 2016年 第3卷 第1期   页码 65-71 doi: 10.15302/J-FASE-2016086

摘要: Porcine reproductive and respiratory syndrome (PRRS) is characterized by reproductive failures in sows and respiratory diseases in pigs of all ages. PRRS virus (PRRSV) is its causative agent and has caused huge economic losses in the swine industry. Porcine sialoadhesin (pSn) is a putative receptor of PRRSV. Previous studies have shown that a pSn V-set Ig-like domain is significant in PRRSV infection. However, its structural details are not fully known, hindering our deep understanding of PRRSV infection. In this study, we successfully cloned, expressed and purified the pSn V-set Ig-like domain in S2 cells. Then we tried to crystallize the target protein and predicted its structure. This will establish the foundation for the further structural study of pSn, deepen our understanding of the invasion mechanism of PRRSV, and support the structural information for the development of clinical drugs and vaccines against PRRSV.

关键词: PRRSV     porcine sialoadhesin     V-set Ig-like domain     Drosophila S2 cell     crystallization    

Structural optimization of typical rigid links in a parallel kinematic machine

Xinjun LIU, Zhidong LI, Xiang CHEN

《机械工程前沿(英文)》 2011年 第6卷 第3期   页码 344-353 doi: 10.1007/s11465-011-0227-x

摘要:

The motion dynamics and accuracy of parallel kinematic machines largely depend on the weights and rigidity of typical rigid links. Therefore, these parts should be designed in such a way that they are light but rigid. This work employs the techniques of topology and size optimization to design two typical rigid links of a parallel kinematic machine (PKM) and subsequently obtains applicable structures for them. The calculation models are established, and a new algorithm called the Guide-Weight method is introduced to solve topology optimization problems. The commercial software Ansys is used to perform size optimization.

关键词: topology optimization     size optimization     parallel kinematic machine (PKM)    

Design and analysis of electrothermal metasurfaces

Xiu LIU, Zhuo LI, Zexiao WANG, Hyeong Seok YUN, Sheng SHEN

《能源前沿(英文)》 2023年 第17卷 第1期   页码 134-140 doi: 10.1007/s11708-022-0841-9

摘要: Electrothermal metasurfaces have garnered considerable attention owing to their ability to dynamically control thermal infrared radiation. Although previous studies were mainly focused on metasurfaces with infinite unit cells, in practice, the finite-size effect can be a critical design factor for developing thermal metasurfaces with fast response and broad temperature uniformity. Here, we study the thermal metasurfaces consisting of gold nanorods with a finite array size, which can achieve a resonance close to that of the infinite case with only several periods. More importantly, such a small footprint due to the finite array size yields response time down to a nanosecond level. Furthermore, the number of the unit cells in the direction perpendicular to the axis of nanorods is found to be insensitive to the resonance and response time; thus, providing a tunable aspect ratio that can boost the temperature uniformity in the sub-Kelvin level.

关键词: modulated thermal infrared radiation     metasurface     nanosecond response time     sub-Kelvin temperature uniformity     finite size     aspect ratio    

Time-domain and frequency-domain approaches to identification of bridge flutter derivatives

Zhengqing CHEN

《结构与土木工程前沿(英文)》 2009年 第3卷 第2期   页码 173-179 doi: 10.1007/s11709-009-0034-1

摘要: Flutter derivatives are essential for flutter analysis of long-span bridges, and they are generally identified from the vibration testing data of a sectional model suspended in a wind tunnel. Making use of the forced vibration testing data of three sectional models, namely, a thin-plate model, a nearly streamlined model, and a bluff-body model, a comparative study was made to identify the flutter derivatives of each model by using a time-domain method and a frequency-domain method. It was shown that all the flutter derivatives of the thin-plate model identified with the frequency-domain method and time-domain method, respectively, agree very well. Moreover, some of the flutter derivatives of each of the other two models identified with the two methods deviate to some extent. More precisely, the frequency-domain method usually results in smooth curves of the flutter derivatives. The formulation of time-domain method makes the identification results of flutter derivatives relatively sensitive to the signal phase lag between vibration state vector and aerodynamic forces and also prone to be disturbed by noise and nonlinearity.

关键词: long-span bridges     wind-induced vibration     flutter derivatives     forced vibration test     time-domain method     frequency-domain method    

Entity and relation extraction with rule-guided dictionary as domain knowledge

《工程管理前沿(英文)》   页码 610-622 doi: 10.1007/s42524-022-0226-0

摘要: Entity and relation extraction is an indispensable part of domain knowledge graph construction, which can serve relevant knowledge needs in a specific domain, such as providing support for product research, sales, risk control, and domain hotspot analysis. The existing entity and relation extraction methods that depend on pretrained models have shown promising performance on open datasets. However, the performance of these methods degrades when they face domain-specific datasets. Entity extraction models treat characters as basic semantic units while ignoring known character dependency in specific domains. Relation extraction is based on the hypothesis that the relations hidden in sentences are unified, thereby neglecting that relations may be diverse in different entity tuples. To address the problems above, this paper first introduced prior knowledge composed of domain dictionaries to enhance characters’ dependence. Second, domain rules were built to eliminate noise in entity relations and promote potential entity relation extraction. Finally, experiments were designed to verify the effectiveness of our proposed methods. Experimental results on two domains, including laser industry and unmanned ship, showed the superiority of our methods. The F1 value on laser industry entity, unmanned ship entity, laser industry relation, and unmanned ship relation datasets is improved by +1%, +6%, +2%, and +1%, respectively. In addition, the extraction accuracy of entity relation triplet reaches 83% and 76% on laser industry entity pair and unmanned ship entity pair datasets, respectively.

关键词: entity extraction     relation extraction     prior knowledge     domain rule    

Damage identification in connections of moment frames using time domain responses and an optimization

《结构与土木工程前沿(英文)》 2021年 第15卷 第4期   页码 851-866 doi: 10.1007/s11709-021-0739-3

摘要: Damage is defined as changes to the material and/or geometric properties of a structural system, comprising changes to the boundary conditions and system connectivity, adversely affecting the system’s performance. Inspecting the elements of structures, particularly critical components, is vital to evaluate the structural lifespan and safety. In this study, an optimization-based method for joint damage identification of moment frames using the time-domain responses is introduced. The beam-to-column connection in a metallic moment frame structure is modeled by a zero-length rotational spring at both ends of the beam element. For each connection, an end-fixity factor is specified, which changes between 0 and 1. Then, the problem of joint damage identification is converted to a standard optimization problem. An objective function is defined using the nodal point accelerations extracted from the damaged structure and an analytical model of the structure in which the nodal accelerations are obtained using the Newmark procedure. The optimization problem is solved by an improved differential evolution algorithm (IDEA) for identifying the location and severity of the damage. To assess the capability of the proposed method, two numerical examples via different damage scenarios are considered. Then, a comparison between the proposed method and the existing damage identification method is provided. The outcomes reveal the high efficiency of the proposed method for finding the severity and location of joint damage considering noise effects.

关键词: damage identification     beam-to-column connection     time-domain response     optimization    

The size distribution of airborne bacteria and human pathogenic bacteria in a commercial composting plant

《环境科学与工程前沿(英文)》 2021年 第15卷 第3期 doi: 10.1007/s11783-020-1356-4

摘要:

•Bacterial concentrations from eight stages were 104–105copies/m3.

关键词: Size distribution     Airborne bacteria     Biological diversity     Human pathogenic bacteria     Composting plants    

Particle size distribution and shape control of Au nanoparticles used for particle gun

S. Kida, M. Ichiji, J. Watanabe, I. Hirasawa

《化学科学与工程前沿(英文)》 2013年 第7卷 第1期   页码 60-64 doi: 10.1007/s11705-013-1313-x

摘要: Au nanoparticles are expected for the media to transfer genes into plants. However, the control of particle size distribution (PSD) and shape of Au nanoparticles is too difficult to design and prepare particles with suitable quality for the gene supporting media. Reduction crystallization experiments were performed in aqueous solution in order to clarify the effect of feeding conditions such as feeding profile, feeding rate, and feeding amount on PSD and shape of Au nanoparticles. Ascorbic acid (AsA) was selected as a reducing agent because it is safe for plants. Au particles of 50 nm, 50–200 nm, and 150–400 nm were obtained in batch operation, single-jet, and double-jet, respectively. Moreover, in single-jet and double-jet, the mean size of the obtained Au particles increases with the decrease of feeding rate or the increase of feeding amount. It is concluded that PSD of Au nanoparticles can be controlled in the range of 50–400 nm by changing feeding conditions of AsA and HAuCl aqueous solution.

关键词: reduction crystallization     particle size distribution     gene transferring media    

Terahertz time-domain spectroscopy of high-pressure flames

Jason BASSI, Mark STRINGER, Bob MILES, Yang ZHANG

《能源前沿(英文)》 2009年 第3卷 第2期   页码 123-133 doi: 10.1007/s11708-009-0033-x

摘要: Laser spectroscopy in the visible and near infrared is widely used as a diagnostic tool for combustion devices, but this approach is difficult at high pressures within a sooty flame itself. High soot concentrations render flames opaque to visible light, but they remain transparent to far-infrared or terahertz (THz) radiation. The first far-infrared absorption spectra, to the best of our knowledge, of sooty, non-premixed, ethylene high-pressure flames covering the region of 0.2-2.5 THz is presented. A specially designed high-pressure burner which is optically accessible to THz radiation has been built allowing flame transmission measurements up to pressures of 1.6 MPa. Calculations of the theoretical combustion species absorption spectra in the 0.2-3 THz range have shown that almost all the observable features arise from H O. A few OH (1.84 and 2.51 THz), CH (2.58 THz), and NH (1.77 and 2.95 THz) absorption lines are also observable in principle. A large number of H O absorption lines are observed in the ground vibrational in a laminar non-premixed, sooty flame (ethylene) at pressures up to 1.6 MPa.

关键词: terahertz time-domain spectroscopy     high-pressure flames     H2O absorption lines    

A better way to do small-for-size liver transplantation in rats

null

《医学前沿(英文)》 2011年 第5卷 第1期   页码 106-110 doi: 10.1007/s11684-011-0113-2

摘要:

Establishing a model for small-for-size liver transplantation is the basis for this study of partial and living donor graft liver transplantation. This study aims to explore a simpler and more effective way of establishing a 30% small-for-size liver transplantation in rats. Sprague-Dawley rats were selected as the donors and recipients. Small-for-size orthotopic liver transplantation was performed using Kamada’s two-cuff method. The donor’s liver was flushed via the abdominal aorta and hepatectomy was performed in situ. The animals were divided into three groups depending on the graft selected, with 40 pairs of rats in each group. In group I, the median lobe of the liver was used as graft; in group II, the right half of the median lobe and the right lobe were used as graft; and in group III, the median and right lobes were used as graft. In groups I and II, the bodyweights of donors were the same as those of recipients; however, in group III the bodyweights of donors were 100–120 g less than those of the recipients. The duration needed for transplantation, the 7-day survival rates, and the technical complication rates were compared among these three groups. The time required for hepatectomy was shorter in group III compared with groups I and II (8.8?±?0.7 min vs. 11.5?±?1.1 min and 10.1?±?1.0 min, P = 0.001). The cold ischemia time for the grafts, the anhepatic times, and the transplantation times for the recipients were not significantly different among the three groups. Compared with groups I and II, the incidence of bleeding, bile leakage, and inferior vena caval strictures were significantly decreased in group III (P<0.05). No significant differences between the three groups were found based on other complications after the operation (P>0.05). Group III had better 7-day survival rates and longer median survival times but the differences were not statistically significant. The method of small for donor bodyweight using the median and right lobes for grafting may be a more effective and simpler way of establishing a 30% small-for-size liver transplantation in rats, as shown by the shorter hepatectomy time and the occurrence of fewer complications after the operation.

关键词: liver transplantation     small-for-size     rats    

标题 作者 时间 类型 操作

Thermal reffusivity: uncovering phonon behavior, structural defects, and domain size

Yangsu XIE, Bowen ZHU, Jing LIU, Zaoli XU, Xinwei WANG

期刊论文

Influence evaluation of loading conditions during pressurized thermal shock transients based on thermal-hydraulicsand structural analyses

Jinya KATSUYAMA, Shumpei UNO, Tadashi WATANABE, Yinsheng LI

期刊论文

Variation in humic and fulvic acids during thermal sludge treatment assessed by size fractionation, elementary

Yuning YANG,Huan LI,Jinyi LI

期刊论文

A super-element approach for structural identification in time domain

LI Jie, ZHAO Xin

期刊论文

Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

期刊论文

Structural prediction of porcine sialoadhesin V-set Ig-like domain sheds some light on its role in porcine

Jie HOU,Rui LI,Hongfang MA,Songlin QIAO,Gaiping ZHANG

期刊论文

Structural optimization of typical rigid links in a parallel kinematic machine

Xinjun LIU, Zhidong LI, Xiang CHEN

期刊论文

Design and analysis of electrothermal metasurfaces

Xiu LIU, Zhuo LI, Zexiao WANG, Hyeong Seok YUN, Sheng SHEN

期刊论文

Time-domain and frequency-domain approaches to identification of bridge flutter derivatives

Zhengqing CHEN

期刊论文

Entity and relation extraction with rule-guided dictionary as domain knowledge

期刊论文

Damage identification in connections of moment frames using time domain responses and an optimization

期刊论文

The size distribution of airborne bacteria and human pathogenic bacteria in a commercial composting plant

期刊论文

Particle size distribution and shape control of Au nanoparticles used for particle gun

S. Kida, M. Ichiji, J. Watanabe, I. Hirasawa

期刊论文

Terahertz time-domain spectroscopy of high-pressure flames

Jason BASSI, Mark STRINGER, Bob MILES, Yang ZHANG

期刊论文

A better way to do small-for-size liver transplantation in rats

null

期刊论文